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Explosions, Properties

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Explosions, Properties

The National Fire Protection Association (NFPA), the Compressed Gas Association (CGA), and the Society of Fire Protection Engineers (SFPE)   represent the U.S. fire protection and engineering community, and these organizations publish handbooks and standards/guidelines that describe the properties of hydrogen. There are many other organizations and documents that provide similar…

Category: Properties

This is an impossible question to answer without greater understanding of the quantities of hydrogen involved, the types of vessels involved, and the atmospheric conditions. Several companies offer software to model such releases. It’s important to note that there is a high probability of ignition either during the vessel rupture or from nearby ignition sources.

Category: Properties

Vaporization of a trapped volume of LH2 will lead to significant increase in pressure due to the very large expansion ratio as the liquid converts to gas. Relief devices are required since the pressure increase is likely to be far in excess of the pressure rating of the system. When vaporized as part of a flowing process, pressure will not increase. As the LH2 is warmed, it undergoes a phase…

Category: Properties

A pressure of 600 kPa (87 psi) is relatively moderate, so the combustion properties are similar to those at atmospheric pressure where the autoignition temperature of hydrogen is 585°C. 

Category: Properties

H2-air flammability limits vary with temperature  . The H2-air lower flammability limit is virtually the same as the H2-O2 lower limit. However, the H2-O2 upper flammability limit increases substantially to about 95% at room temperature and gets even higher at elevated temperatures.

Category: Properties

Most common odorants will contaminate fuel cells. Additionally, hydrogen's small molecule and high buoyancy make it challenging to find a compatible odorant. Research is being conducted on fuel cell compatible odorants, but there are none currently in use. Like liquefied natural gas, liquid hydrogen also can’t be odorized due to its cryogenic temperature.

Category: Properties
Keywords: Odorant, Odor

Hydrogen flames can be nearly invisible in daylight, especially at low flowrates. The concentration of hydrogen does not have much effect on the color of the flame. Many hydrogen incidents or fires will have a bright orange hue, or even yellow flames. The color is primarily caused by contaminants that is either naturally in the air in certain environments, swept into the air during the release…

Category: Properties
Keywords: Fire, Flame

Yes, small flowrate vents may be invisible, particularly in daylight. Sometimes it may still be possible to see heat striations in the air from the heat generated by the fire, but it can be difficult to discern at low flowrates. 

Category:
Keywords: Vent, Flame, Flow

Several organizations published a paper together on this topic in 2017 (see attached). Based on comparisons with tests and CFD simulations, the following conclusions were drawn:

  1. The gas concentration for vapor cloud explosion blast load calculations for H2 jets can be limited to approximately 10% to 75%. Note that testing for H2-air VCEs in congested environments has been performed…
Category: Explosions

The “Hydrogen Ready Appliances Assessment Report” published by the Northwest Energy Efficiency Alliance (NEEA) in February, 2023, is one of the most recent studies on this topic.  Several key items from the report pertaining to this question include the following:

1.    “There appears to be growing consensus that blends of up to 20% or perhaps even 30% are…

Category: Properties
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