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If the concentration of hydrogen is less than the Lower Flammability Limit (LFL) of 4% in an inert gas, it is unlikely that a leak of this gas mix will form a flammable mixture as it dilutes into air. For example, industry uses ‘forming gas’, a mixture of 4 to 5% H2 in nitrogen, as an oxide reducing agent in materials processing furnaces and soldering operations. This mixture can also be used…
See H2Tools, Best Practices: Purging, for a description of different purging approaches for hydrogen systems.
Because hydrogen leaks frequently ignite, and because about half the time the ignition source is not identified, when evaluating hazards with hydrogen leaks, many people just assume the leak will be ignited. Note that consideration needs to be made for what may happen with immediate ignition (jet fire) and what may happen with delayed ignition (explosion).
It is still important to…
There are several resources that can help review designs, such as the Hydrogen Safety Panel and other outside consultants that are members of the Center for Hydrogen Safety.
Sprinkler systems and other fire suppression means are prescribed per building and fire codes to limit fire spread to other materials. In the case of a hydrogen leak and fire, it is best practice to isolate the hydrogen source, and let any residual hydrogen gas burn out. Even if the initial fire is extinguished, additional leaking hydrogen may accumulate and ignite with the potential for an…
In general, indoor storage should be limited and the use of hydrogen indoors should be the least necessary. Look to store flammable gases outdoors in dedicated protected area when practicable. Check to see what adopted building and fire codes in your jurisdiction say. NFPA 2, Hydrogen Technology Code, Sections 6.4.1 and 16.3 prescribe requirements to limit hydrogen storage and use in…
Outside storage is generally considered safer and is required for large amounts of gas. Stationary storage should be located outside at a safe distance from structures and ventilation intakes, and protected from vehicle impact.
Hydrogen storage separation distance requirements are typically based on the quantity and pressure of the hydrogen or the piping diameter, depending on the…
In laboratories, 316 stainless steel tubing is frequently the first choice for small flow and pressures less than 2800 psi (19 MPa). See Best Practices: Material Compatibility for hydrogen compatibility with various materials. Always work within manufacturer’s pressure ratings adjusted for temperature. Read and follow…
Rupture discs open very rapidly. Historically, rupture discs opening at high pressure (1000 psig and above) have caused the most damage due to deflagration/detonation. Timing a rupture disc would not be possible. Additionally, how would you have a pilot light on a moving tube trailer? Even with a pilot light at the end of the stack may blow out due to the initial high velocity.
See…
Vent stacks must be designed for a fire at the outlet. The mesh is designed to ensure no blockage of the vent stack by animals/insects.
Additionally, the mesh must be designed for pressure drop to ensure code-compliant back pressure on the relief devices.
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