Best practices for joining metallic tubing
What are best practices for joining metallic tubing?
Flare-less compression style fittings are commonly used. Choose tubing materials and tube wall thicknesses suitable for hydrogen and pressures you are using. Make sure all tubing joints are properly made, mechanically supported to minimize stress and vibration, are in a ventilated space, and are easily accessible for inspection and leak testing.
Extremely low minimum ignition energy (MIE)
With the extremely low minimum ignition energy (MIE) of Hydrogen, is it best to basically consider it as pyrophoric?
Because hydrogen leaks frequently ignite, and because about half the time the ignition source is not identified, when evaluating hazards with hydrogen leaks, many people just assume the leak will be ignited. Note that consideration needs to be made for what may happen with immediate ignition (jet fire) and what may happen with delayed ignition (explosion).
It is still important to minimize the probability of ignition and to minimize the consequences if it does ignite. We do that by properly characterizing hydrogen with all its unique properties, including flammability and low MIE, and by providing the appropriate safeguards prescribed by codes and standards specific to hydrogen. These safeguards include minimum quantities, using proper materials of construction, leak prevention practices, proper ventilation, proper disposal to safe areas, and ignition source control such as the use of non-sparking, electrical grounding, and classified electrical equipment.
Best practices for storage and use of hydrogen cylinders inside the lab
What are the best practices for storage and use of hydrogen cylinders inside the lab?
In general, indoor storage should be limited and the use of hydrogen indoors should be the least necessary. Look to store flammable gases outdoors in dedicated protected area when practicable. Check to see what adopted building and fire codes in your jurisdiction say. NFPA 2, Hydrogen Technology Code, Sections 6.4.1 and 16.3 prescribe requirements to limit hydrogen storage and use in laboratories. NFPA also prescribes requirements for ventilation, gas cabinets, electrical classification, and fume hood operations. Consider outdoor or dedicated storage facilities if you need more than one standard-sized cylinder of hydrogen to support your work.
Removing hydrogen from the piping (turnaround of H2 plant) or after depressurization
It was said purging is not suggested. But how do we remove hydrogen from the piping (turnaround of H2 plant) or after depressurization?
Purging is not recommended as a continuous part of vent stack operation. However, maintenance activity is a transient event and it’s prudent and recommended to purge a vent system prior to performing maintenance. It’s always possible that hydrogen could be leaking internally from a valve or other component and therefore create a hazard. Of particular note, care must be taken that proper isolation of the vent system is performed such that the vent system can’t be inadvertently used during maintenance. Since vent systems and stacks rarely have isolation valves to prevent unintended isolation of relief devices, proper maintenance on the vent system may require the entire system or plant to be taken offline.
Recommendation schedule for vent line opening inspection
What is your recommendation schedule for vent line opening inspection?
We would not open the vent system to inspect the internal piping without a good reason.
It is recommended to check for water in the vent stack trap
- At startup and daily during startup.
- On LH2 tank system, every delivery
- After the 1st rainstorm after a system is installed
- LH2 vent stacks after establishing the baseline above
- After every large venting event
- Quarterly unless baseline requires more frequent
- GH2 stack after baseline
- Check caps are still on quarterly for stationary tubes.
Special precaution for sending H2 to the flare instead of venting it separately
In a plant where other chemicals are sent to a common flare system, is any special precaution needed for sending H2 to the flare instead of venting it separately?
- Understand any reactions the hydrogen can add to what is being vented. For instance, O2/H2 vented in the same stack would not be a good idea.
- Understand all the flow and operating parameters of the streams to ensure no back flow into the hydrogen system or vice versa.
- Ensure the venting/flaring system can handle the hydrogen flow parameters.
Heat flux limit for hitting equipment or people and design code
What is the heat flux limit for hitting equipment or people, and is there a design code?
Recommended limits of heat flux for various exposures is provided in documents such as API Standard 521, the International Fire Code, the National Fire Protection Association and the Society of Fire Protection Engineers. Selection of a specific thermal radiation level is dependent upon a risk analysis. Some salient exposures are listed below.
- 1,577 W/m2 (500 Btu/hr ft2) is defined by API 521 as the heat flux threshold where personnel with appropriate clothing may be continuously exposed. This value is similar to the Society of Fire Protection Engineers “no-harm” heat flux threshold 540 Btu/hr ft2.
- 4,732 W/m2 (1,500 Btu/hr ft2) is defined by API 521 as the heat flux threshold in areas where emergency actions lasting several minutes may be required by personnel without shielding but with appropriate clothing. It is also defined by the International Fire Code as the threshold for exposure to employees for a maximum of 3 minutes.
- 20,000 W/m2 (6,340 Btu/hr ft2) is generally considered the minimum heat flux for the non-piloted ignition of combustible materials, such as wood.
- 25,237 W/m2 (8,000 Btu/hr ft2) is the threshold heat flux imposed by the International Fire Code for non-combustible materials.
NFPA 2 has also published Annex material which provides additional detail on the harm values used for the calculation of separation distances.
Is a change in venting system required for Green Hydrogen projects
Is a change in venting system required for Green Hydrogen projects? If yes, how do green hydrogen projects differ from blue or brown hydrogen projects?
The colors of hydrogen are not different hydrogen molecules. The colors represent the different methods to produce hydrogen. The colors are based on how much carbon is produced into the atmosphere during the manufacture of hydrogen.
That being said there is no difference in hydrogen vent systems design by color, only by the design parameters (i.e. temperature, pressure, flow rate, etc.)
Avoiding air entry and subsequent liquefying/freezing in the LH2 vent line
How can we avoid air entry and subsequent liquefying/freezing in the LH2 vent line?
It is normal for some air ingress to occur from the vent stack outlet. This is not a hazard if the stack has been properly designed to withstand an internal explosion or fire. Once hydrogen flow from a device is initiated, it will sweep out any air that might be in the stack. Generally, if the vent rate is insufficient to sweep the air out, then it’s also insufficient to freeze or liquefy air in the stack. However, it’s important to prevent air from being pulled into the stack from a venturi effect, so leaks or holes where air can enter the vent piping should be eliminated.