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In the case of fuel-rich mixtures like those in the question, the heat of combustion for the mixture should be calculated on the basis of the oxygen content of the mixture. The heat of combustion per mole oxygen is twice the heat of combustion per mole hydrogen, i.e., it is 286*2 kJ per mole O2. You should be able to do the calculations based on this reply.
Assuming this question relates to the roof of the enclosure, there are no design criteria on this topic to the Panel’s knowledge. The key to the design would be ensure that the exhaust ventilation inlet is located at the highest point and that there are no pockets that can capture hydrogen (restrict flow to the exhaust inlet).
Information on Toyota’s repair garage approach is available…
A best practice, even for small hydrogen vents, is to vent to a dedicated vent system outside the building where possible. Several international codes and standards can be used to provide guidance; the Panel recommends discussing the configuration with a local fire official to ensure their required standards are followed. In the U.S. NFPA 2, Hydrogen Technologies Code, has information in…
It is always recommended that the area in which this work would be done be adequately ventilated and in accordance with the Building Code, NFPA 2 and NFPA 45 if applicable. In the Panel’s opinion, it’s recommended that the weight measuring equipment as you’ve described it be designed for Class 1, Group B, Division 2. Also consult with the local authority having jurisdiction as to the…
While HSP members have limited experience with MFCs in experimental setups, the Panel does not consider them to be reliable to provide a positive flow shutoff. For safety, a shutoff valve in series is recommended. Projects will also need to consider hazardous electrical rating and location when flowing H2. Regarding Coriolis mass flow measuring devices, Coriolis flow meters measure mass rate…
It is difficult to provide trustworthy answers to these questions without understanding the design and configuration of the specific installation. It may be best to consult with a pressure systems expert to evaluate the specific installation and uses. The gas provider may also be a good resource for specifics on gas equipment use. Other beneficial resources include the…
This is not an easy question since many factors influence how much hydrogen can be transferred from one vessel at a higher pressure to another one at a lower pressure and the rate at which it can be transferred. The pressure in the higher vessel will fall while that in the lower vessel will rise as gas is transferred, so the flow rate will typically slow down and eventually stop as the…
It varies slightly due to different density of LH2 at different temperatures, but a gallon of LH2 at atmospheric pressure (0 psig) is ~113 SCF of H2. The expansion ratio is about 840:1. In metric units, a liter of LH2 at atmospheric pressure (0 MPa) would expand to about 840 liters of STP of gaseous pressure.
The National Fire Protection Association (NFPA), the Compressed Gas Association (CGA), and the Society of Fire Protection Engineers (SFPE) represent the U.S. fire protection and engineering community, and these organizations publish handbooks and standards/guidelines that describe the properties of hydrogen. There are many other organizations and documents that provide similar…
This is an impossible question to answer without greater understanding of the quantities of hydrogen involved, the types of vessels involved, and the atmospheric conditions. Several companies offer software to model such releases. It’s important to note that there is a high probability of ignition either during the vessel rupture or from nearby ignition sources.
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