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Liquid hydrogen is much less likely to pool than liquified natural gas (LNG) due to its low heat of vaporization. Very large facilities are often equipped with methods to enhance vaporization, such as crushed stone under tanks, as well as diversion systems to allow liquid hydrogen to spill and boil off in a safe area. Care needs to be taken that diversion systems do not create a hazardous…
Codes and standards to address issues like this one are under development, along with applied research and field trials. As with any new application, appropriate codes and standards must be developed to meet public risk targets.
By definition, liquid hydrogen can BLEVE, but this is highly unlikely. Liquid hydrogen is stored in a double wall tank with vacuum insulation. This protects the primary pressure vessel from direct impingement and the very cold liquid provides self-cooling of the vessel walls. Tanks are also equipped with redundant pressure relief systems that are sized for fire exposure.
Underground storage tanks can be either installed in a vault or directly buried. Both offer additional
protection from external impact and fire, but each has unique challenges. Vaults must be properly
ventilated and designed to not create an explosion or asphyxiation risk. Direct burial vessels should not
have any underground leak points and must be protected from corrosion. Both…
Systems should be sited in accordance with national and local standards such as NFPA 2, Hydrogen
Technologies Code. The nature of a trailer filling operation is not much different than a vehicle fueling
station, so the hazards are comparable and similar safeguards such as walls and sensors will apply. These
facilities might be larger and industrial standards and regulations will also…
Exposure between these products is bidirectional. A hazard analysis should consider what happens to
alternate fueling equipment if an incident with one of the fuels occurs. Care must be taken to have the
appropriate separation distance and mitigations according to the applicable codes. Limited experience
with existing stations has shown that these multi-fuel stations can be successful…
Each installation should be evaluated based on the results of a hazard analysis considering both of these
scenarios. Separation distances as listed in documents such as NFPA 2, Hydrogen Technologies Code, are
a minimum starting point but may need to be adjusted based on analysis. Recent work by NFPA 2 has
also included overpressure criteria, but the consequences can vary depending on…
Composite cylinders can be manufactured to standards written by CSA, ASME, and ISO depending on the application and local requirements. Several ISO standards can serve as the basis for composite cylinder approvals within North America.
Documents such as NFPA 2, Hydrogen Technologies Code, and the International Fire Code have quantity thresholds that differentiate requirements for the design of systems and enclosures. However, even the smaller quantities present a hazard under specific conditions, especially for systems that have the potential to release hydrogen into a confined or unvented space. Good engineering judgement…
Leakage/loss depends on the vessel design. Metallic or metallic lined vessels have extremely low permeability and losses through the vessel walls are typically imperceptible. Conversely, Type IV composite vessels which have non-metallic liners are subject to permeation. They are required to meet maximum permeation rates as part of their certification. Fugitive emissions from piping systems can…
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