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Fueling Stations, Hazards Analysis

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Fueling Stations, Hazards Analysis

If liquid hydrogen usage is sufficiently high at the fueling station, there may be no need to vent any boiloff generated from the LH2 storage tank. Boil-off gas should be minimized through system design, but where needed, the boil-off hydrogen along with any other hydrogen released must be vented through a local vent stack which is constructed to safely vent the hydrogen in accordance with CGA…

In the U.S., liquid hydrogen fueling stations and dispensing equipment are addressed within NFPA 2, Chapter 11. Dispensing is covered within Section 11.3. When liquefied hydrogen is used as the supply for high pressure gaseous fueling, then Chapter 10 of NFPA 2 would apply.
ISO standards are also being developed for global LH2 fueling protocols.
 

Flammable hydrogen releases can result in deflagration and transition to a detonation. Whether the
deflagration transitions to a detonation depends on numerous parameters such as cloud size, hydrogen
concentration, confinement, and congestion. Releases into confined or congested areas are more
susceptible to generating significant deflagration over-pressures and more likely to…

There are numerous models that can be used to assess the consequence and risk of leaks and releases.
One such model is HYRAM which is publicly available from Sandia and the US DOE.

Emergency response procedures must be developed for each system based on its design. The
procedures generally include steps to clear personnel from the immediate area, isolate the hydrogen,
shut down the equipment, contact local responders, and protect surrounding equipment/structures until
the hazard is mitigated or the incident is over.

No, this is not a common or preferred approach. Isolating the source of hydrogen is the best safety practice. Water systems could extinguish the flame but allow the gas to continue leaking and result in an explosion if reignited.

Situations where extinguishing a hydrogen leak prior to stopping flow is safer are rare. Hydrogen releases have a high potential for inadvertent re-ignition and subsequent explosion. Some vent stacks might be equipped with an extinguishing system, but these often can be more hazardous than allowing a properly designed vent stack to continue to burn until the source is isolated.

Releases from high pressure hydrogen systems often make a sound. In those cases, sound might be the
easiest way for a person to know there is a hazard. However, leaks can be relatively small and diffuse,
thereby not making much sound, or alternately large and so loud that they can be very difficult to find. In
both cases, it can be hazardous to move into or through an area.

There is no consensus on the “correct” answer. Small leaks of short duration have a much lower
probability of ignition compared to large releases. Ignition probability is affected by the operating
conditions, whether the release is from a leak or vent stack, and the surrounding environment. Since the
probability of ignition is high, hazard analyses will usually assume the hydrogen…

Static is a frequent source of ignition attributed to various hydrogen releases. Low levels of static
electricity are sufficient to ignite hydrogen – air mixtures. Static charges can be created by the
atmospheric disturbances and storms, high velocity particles entrained by the gas impacting stationary
objects, and human activity. Grounding of equipment and operators is important to…

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